SUPER GLUE LIQUID

Material Safety Data Sheet

This material is hazardous according to criteria of NOHSC
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail.

1. Identification of the substance/preparation and of the company/undertaking

Product Name: DYNAGRIP SUPER GLUE LIQUID

Supplier: AFC International Pty. Ltd..
ABN: 76 082 316 783
Street Address: 21-23 Hobart Street,
Riverstone,
New South Wales 2765
Australia
Telephone Number: +61 2 9627 7125
Facsimile: +61 2 9627 7126

Emergency Telephone: 0412 614 580 (24 HOURS)

Part Number: 49403 Issued: 10/03/2004 Version 2

2. Composition/Information on Ingredients

Product Description: One part Cyanoacrylate based liquid glue, formulated to give instant and high strength bonds to metals, plastics, china and rubber. Dynagrip Super Glue Liquid has been designed for use on non-porous surfaces.

COMPOSITION
                                                                                         %                     CAS #                  Risk Phrases
Ethyl Cyanacrylate                                                         95-100                7085-85-0            R36/R38/R42/R43
Poly (Methyl Methacrylate)                                            3-5                      9011-14-17          R36/R38/R42/R43
Hydroquinone                                                                0.1-0.5                123-31-9              R36/R38/R42/R43

3. Hazards Identification

Threshold Limit Value: No Criteria for Measurement. Not yet established. Estimated 2ppm
Risk Phrases: Irritating to eyes and skin. May cause sensitisation by skin contact. Prolonged and
repeated overexposure to vapours may produce allergic reactions with asthma-like
symptoms in sensitive individual.Can cause instantaneous bonding of skin.
Poisons Schedule: S5 Caution

4. First-aid Measures

For advice, contact a Poisons Information Centre (Phone eg. Australia 131 126; New Zealand 0 800 764766) or a doctor.

Skin: Immerse bonded surface in warm soapy water. Peel or roll surface apart with aid of blunt
edge. DO NOT PULL A PART WITH DIRECT OPPOSING ACTION.
Burns should be treated normally after the lump of cyanoacrylate is released from the
tissue
Inhalation: Remove victim to fresh air.
Eye Contact: Flush with warm water and apply guaze pad. Eyes will open within 1-4 days. Seek medical assistance. Transport to hospital or medical centre.
Ingestion: Apply warm water to mouth. Peel or roll lips apart. If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical assistance.
Notes to physician: Treat symptomatically. Effects may be delayed.

5. Fire-fighting Measures

Specific Hazards: Possible exothermic reaction with fume generation. Combustible liquid.
Fire-fighting advice: On burning will emit toxic fumes, including those of, oxides of carbon and
oxides of nitrogen. Fire fighters to wear self-contained breathing apparatus
and suitable protective clothing if risk of exposure to vapour or products of combustion
Suitable Extinguishing Media: Water, fog (or if unavailable fine water spray), foam, dry agent (carbon dioxide, dry chemical powder).

6. Accidental Release Measures

NOTE : Super Glue cures and bonds on immediate exposure to air.

SMALL SPILLS: Use cautious judgement when cleaning spills. Flood with water to polymerise (cure) and soak up with an inert absorbent. Sweep up or scrape up and dispose as dry waste. Wear protective equipment to prevent skin and eye contact. Flush area with water spray to remove residue. Dispose of flush legally.

LARGE SPILLS: Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contact and breathing in vapours. Flood with water to polymerise (cure) and soak up with an inert material such as clay or sand. Sweep or scrape up and dispose as dry waste. Collect and seal in properly labelled containers or drums for disposal. Cured material can only be removed by cutting or abrasion. If contamination of sewers or waterways has occurred advise local emergency services.

Classified as a Cl (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations.

7. Handling and Storage

Handling advice: Avoid skin and eye contact.

Storage advice: Store in cool place and out of direct sunlight. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Keep containers closed when not in use - check regularly for leaks.

Classified as a Cl (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations.

8. Exposure Controls/Personal Protection

Occupational Exposure Limits:
No value assigned for this specific material by the National Occupational Health and Safety Commission.

Engineering Control Measures:
Use in well ventilated areas. Keep containers closed when not in use.

Personal Protective Equipment:
Respiratory Protection: Wear organic vapour respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.

Ventilation: Use only with adequate ventilation. Local exhaust is recommended. Mechanical exhaust can be used as a back up system.

Protective Gloves: Chemical resistant gloves such as Polyethylene. Do not use rubber or cotton.

Eye Protection: Approved safety glasses or goggles with side shields

Protective Clothing: Polyethylene/Polypropylene coats or aprons. Do not use rubber or cotton.

9. Physical and Chemical Properties
Physical state: Clear liquid
Odour: Sharp, irritating
Specific Gravity: 1.08
Relative Vapour Density (air=l): Less than 0.2mm at 27C
Vapour Pressure (26C): 3mm approximate
Flash Point (oC): 85
% Non Volatile 76% by volume
Solubility in water (g/L): Polymerised by water
Boiling Point/Range (oC): >145
Evaporation Rate: NA

10. Stability and Reactivity

Stable under normal conditions

Conditions to avoid: Polymerised by contact with water, amines and basic materials.
Hazardous exothermic reaction may occur.

11. Toxicological Information
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Ingestion: Swallowing can result in nausea and gastrointestinal irritation.
Eye contact: An eye irritant.
Skin contact: Contact with skin will result in burning and bonding with irritation. A skin sensitiser. Repeated or prolonged skin contact may lead to allergic contact dermatitis.
Inhalation: Material may be irritant to the mucous membranes of the respiratory tract (airways). Asthma like systems may develop.

Long Term Effects:
No information available for the product.

Toxicological Data:
No LD50 data available for the product.

12. Ecotoxicological Information

Avoid contaminating waterways.

13. Disposal Considerations

Incinerate in accordance with EPA and local Regulations
Refer to Waste Management Authority. Dispose of material through a licensed waste contractor.

14. Transport Information

Road and Rail Transport
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail.

Marine Transport
Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea.

Air Transport
Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air.

15. Regulatory Information

Classification: This material is hazardous according to criteria of NOHSC.
Xi: Irritant

Risk Phrase(s): R36/38: Irritating to eyes and skin.
R42: May cause SENSITISATION by inhalation
R43: May cause SENSITISATION by skin contact

Safety Phrase(s): S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek Medical advice.

S28: After contact with skin, wash immediately with plenty of soap and water.
S36/S37/S39: Wear suitable protective clothing, gloves, eye and face protection.

Poisons Schedule: S5 Caution.

All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).

16. Other Information

Contact Point: AFC International P/L Technical Department

Phone: 61 2 9627 7125 (International) Local 02 9627 7125
Fax: 61 2 9627 7126 (International) Local 02 9627 7126
Mobile: 0412 614 580

Reason for Issue:
First Revision of Primary MSDS

This MSDS summarises to the best of the knowledge of AFC International Pty. Ltd. at the date of issue, the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace. Since AFC International Pty. Ltd. cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material.

If clarification or further information is needed, the user should contact AFC International Pty. Ltd at the contact details on page 1.

This MSDS summarises to the best of the knowledge of AFC International at the date of issue, the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace. Since AFC International Pty. Ltd. cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material.

SUPER GLUE GEL

Material Safety Data Sheet

This material is hazardous according to criteria of NOHSC
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail.

1. Identification of the substance/preparation and of the company/undertaking

Product Name: DYNAGRIP SUPER GLUE GEL

Supplier: AFC International Pty. Ltd..
ABN: 76 082 316 783
Street Address: 21-23 Hobart Street,
Riverstone,
New South Wales 2765
Australia
Telephone Number: +61 2 9627 7125
Facsimile: +61 2 9627 7126

Emergency Telephone: 0412 614 580 (24 HOURS)

Part Number: 49404 Issued: 10/03/2004 Version 2

2. Composition/Information on Ingredients

Product Description: One part Cyanoacrylate based gel glue, formulated to give instant and high strength bonds to metals, plastics, china and rubber. Dynagrip Super Glue Gel has been designed for use on non-porous surfaces.

COMPOSITION
                                                                                        %                   CAS #                        Risk Phrases
Ethyl Cyanoacrylate                                                      85-90                7085-85-0                  R36/R38/R42/R43
Poly (Methyl Methacrylate)                                           5-10                  9011-14-17                R36/R38/R42/R43
Silica, Amorphous Treated                                           5-10                  112945-52-5
Hydroquinone                                                               0.1-0.5              123-31-9                    R36/R38/R42/R43

3. Hazards Identification

Threshold Limit Value: No Criteria for Measurement. Not yet established. Estimated 2ppm
Risk Phrases: Irritating to eyes and skin. May cause sensitisation by skin contact. Prolonged and
repeated overexposure to vapours may produce allergic reactions with asthma-like
symptoms in sensitive individual.
Can cause instantaneous bonding of skin.
Poisons Schedule: S5 Caution

4. First-aid Measures

For advice, contact a Poisons Information Centre (Phone eg. Australia 131 126; New Zealand 0 800 764766) or a doctor.

Skin: Immerse bonded surface in warm soapy water. Peel or roll surface apart with aid of blunt
edge. DO NOT PULL A PART WITH DIRECT OPPOSING ACTION.
Burns should be treated normally after the lump of cyanoacrylate is released from the tissue
Inhalation: Remove victim to fresh air.
Eye Contact: Flush with warm water and apply gauze pad. Eyes will open within 1-4 days. Seek medical assistance. Transport to hospital or medical centre.
Ingestion: Apply warm water to mouth. Peel or roll lips apart. If swallowed, do NOT induce vomiting. Give a glass of water. Seek immediate medical assistance.
Notes to physician: Treat symptomatically. Effects may be delayed.

5. Fire-fighting Measures

Specific Hazards: Possible exothermic reaction with fume generation. Combustible liquid.
Fire-fighting advice: On burning will emit toxic fumes, including those of, oxides of carbon and oxides of nitrogen. Fire fighters to wear self-contained breathing apparatus and suitable protective clothing if risk of exposure to vapour or products of combustion
Suitable Extinguishing Media: Water, fog (or if unavailable fine water spray), foam, dry agent (carbon dioxide, dry chemical powder).

6. Accidental Release Measures

NOTE : Super Glue cures and bonds on immediate exposure to air.

SMALL SPILLS: Use cautious judgement when cleaning spills. Flood with water to polymerise (cure) and soak up with an inert absorbent. Sweep up or scrape up and dispose as dry waste. Wear protective equipment to prevent skin and eye contact. Flush area with water spray to remove residue. Dispose of flush legally.

LARGE SPILLS: Avoid accidents, clean up immediately. Wear protective equipment to prevent skin and eye contact and breathing in vapours. Flood with water to polymerise (cure) and soak up with an inert material such as clay or sand. Sweep or scrape up and dispose as dry waste. Collect and seal in properly labelled containers or drums for disposal. Cured material can only be removed by cutting or abrasion. If contamination of sewers or waterways has occurred advise local emergency services.

Classified as a Cl (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations.

7. Handling and Storage

Handling advice: Avoid skin and eye contact.

Storage advice: Store in cool place and out of direct sunlight. Store away from foodstuffs. Store away from incompatible materials described in Section 10. Keep containers closed when not in use - check regularly for leaks.

Classified as a Cl (COMBUSTIBLE LIQUID) for the purpose of storage and handling, in accordance with the requirements of AS 1940. Refer to State Regulations for storage and transport requirements.

This material is a Scheduled Poison S5 and must be stored, maintained and used in accordance with the relevant regulations.

8. Exposure Controls/Personal Protection

Occupational Exposure Limits:
No value assigned for this specific material by the National Occupational Health and Safety Commission.

Engineering Control Measures: Use in well ventilated areas. Keep containers closed when not in use.

Personal Protective Equipment:
Respiratory Protection: Wear organic vapour respirator meeting the requirements of AS/NZS 1715 and AS/NZS 1716.

Ventilation: Use only with adequate ventilation. Local exhaust is recommended.Mechanical exhaust can be used as a back up system.

Protective Gloves: Chemical resistant gloves such as Polyethylene. Do not use rubber or cotton.

Eye Protection: Approved safety glasses or goggles with side shields

Protective Clothing: Polyethylene/Polypropylene coats or aprons. Do not use rubber or cotton.

9. Physical and Chemical Properties
Physical state: Clear gel
Odour: Sharp, irritating
Specific Gravity: 1.08
Relative Vapour Density (air=l): Less than 0.2mm at 27C
Vapour Pressure (26C): 3mm approximate
Flash Point (oC): 85
% Non Volatile 76% by volume
Solubility in water (g/L): Polymerised by water
Boiling Point/Range (oC): >145
Evaporation Rate: NA

10. Stability and Reactivity

Stable under normal conditions

Conditions to avoid: Polymerised by contact with water, amines and basic materials.
Hazardous exothermic reaction may occur.

11. Toxicological Information
No adverse health effects expected if the product is handled in accordance with this Safety Data Sheet and the product label. Symptoms or effects that may arise if the product is mishandled and overexposure occurs are:

Ingestion: Swallowing can result in nausea and gastrointestinal irritation.
Eye contact: An eye irritant.
Skin contact: Contact with skin will result in burning and bonding with irritation. A skin sensitiser. Repeated or prolonged skin contact may lead to allergic contact dermatitis.
Inhalation: Material may be irritant to the mucous membranes of the respiratory tract (airways). Asthma like systems may develop.

Long Term Effects:
No information available for the product.

Toxicological Data:
No LD50 data available for the product.

12. Ecotoxicological Information

Avoid contaminating waterways.

13. Disposal Considerations

Incinerate in accordance with EPA and local Regulations
Refer to Waste Management Authority. Dispose of material through a licensed waste contractor.

14. Transport Information

Road and Rail Transport
Not classified as Dangerous Goods by the criteria of the Australian Dangerous Goods Code (ADG Code) for transport by Road and Rail.

Marine Transport
Not classified as Dangerous Goods by the criteria of the International Maritime Dangerous Goods Code (IMDG Code) for transport by sea.

Air Transport
Not classified as Dangerous Goods by the criteria of the International Air Transport Association (IATA) Dangerous Goods Regulations for transport by air.

15. Regulatory Information

Classification: This material is hazardous according to criteria of NOHSC.
Xi: Irritant

Risk Phrase(s): R36/38: Irritating to eyes and skin.
R42: May cause SENSITISATION by inhalation
R43: May cause SENSITISATION by skin contact

Safety Phrase(s): S24/25: Avoid contact with skin and eyes.
S26: In case of contact with eyes, rinse immediately with plenty of water and
seek Medical advice.

S28: After contact with skin, wash immediately with plenty of soap and water.
S36/S37/S39: Wear suitable protective clothing, gloves, eye and face protection.

Poisons Schedule: S5 Caution.

All the constituents of this material are listed on the Australian Inventory of Chemical Substances (AICS).

16. Other Information

Contact Point: AFC International P/L Technical Department

Phone: 61 2 9627 7125 (International) Local 02 9627 7125
Fax: 61 2 9627 7126 (International) Local 02 9627 7126
Mobile: 0412 614 580

Reason for Issue:
First Revision of Primary MSDS

This MSDS summarises to the best of the knowledge of AFC International Pty. Ltd. at the date of issue, the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace. Since AFC International Pty. Ltd. cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material.

If clarification or further information is needed, the user should contact AFC International Pty. Ltd at the contact details on page 1.

This MSDS summarises to the best of the knowledge of AFC International at the date of issue, the chemical health and safety hazards of the material and general guidance on how to safely handle the material in the workplace. Since AFC International Pty. Ltd. cannot anticipate or control the conditions under which the product may be used, each user must, prior to usage, assess and control the risks arising from its use of the material.

 

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